1,5-비스(다이페닐포스피노)펜테인

1,5-비스(다이페닐포스피노)펜테인
이름
	별칭 DPPP
식별자
CAS 번호	27721-02-4 ;
3D 모델 (JSmol)	Interactive image;
약어	dpppe
ChEMBL	ChEMBL68967;
ChemSpider	2015213;
ECHA InfoCard	100.154.700
EC 번호	626-285-7;
PubChem CID	2733414;
CompTox Dashboard (EPA)	DTXSID80369900 ;
	InChI InChI=1S/C29H30P2/c1-6-16-26(17-7-1)30(27-18-8-2-9-19-27)24-14-5-15-25-31(28-20-10-3-11-21-28)29-22-12-4-13-23-29/h1-4,6-13,16-23H,5,14-15,24-25H2 Key: MZFPAWGWFDGCHP-UHFFFAOYSA-N;
	SMILES C1=CC=C(C=C1)P(CCCCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4;
성질
화학식	C29H30P2
몰 질량	440.507 g·mol−1
겉보기	흰색 고체
녹는점	41-44 oC
	달리 명시된 경우를 제외하면, 표준상태(25 °C [77 °F], 100 kPa)에서 물질의 정보가 제공됨. 정보상자 각주

1,5-비스(다이페닐포스피노)펜테인(영어: 1,5-bis(diphenylphosphino)pentane)은 화학식이 C₂₉H₃₀P₂인 유기 인 화합물이다. 1,5-비스(다이페닐포스피노)펜테인은 1,5-다이브로모펜테인을 수산화 세슘이 있는 상태에서 리튬 다이페닐포스파이드^[2] 또는 다이페닐포스핀과 반응시켜 제조할 수 있다.^[3] 1,5-비스(다이페닐포스피노)펜테인은 아이오딘화 구리(I)와 반응하여 발광성 이핵 복합체인 [CuIPh₂P(CH₂)₅PPh₂]₂을 생성한다.^[4]

같이 보기[편집]

유기 인 화합물

각주[편집]

↑ Shatunov, V.V.; Korlyukov, A.A.; Lebedev, A.V.; Sheludyakov, V.D.; Kozyrkin, B.I.; Orlov, V.Yu. (2011). “The synthesis and deep purification of GaEt3. Reversible complexation of adducts MAlk3 (M = Al, Ga, In; Alk = Me, Et) with phenylphosphines”. 《Journal of Organometallic Chemistry》 (Elsevier BV) 696 (10): 2238–2251. doi:10.1016/j.jorganchem.2010.11.044. ISSN 0022-328X.
↑ Chou, Ta Shue; Yuan, Jeh Jing; Tsao, Chung Huang (1985). “Ultrasonic acceleration of the reductive cleavage of phosphorus-carbon bonds with lithium metal. A simple preparation of tertiary phosphines”. 《Journal of Chemical Research, Synopses》 (1): 18–19. ISSN 0308-2342. .
↑ Honaker, Matthew T.; Salvatore, Ralph Nicholas (2004년 2월 1일). “A MILD AND EFFICIENT CsOH-PROMOTED SYNTHESIS OF DITERTIARY PHOSPHINES”. 《Phosphorus, Sulfur, and Silicon and the Related Elements》 (Informa UK Limited) 179 (2): 277–283. doi:10.1080/10426500490262261. ISSN 1042-6507. S2CID 98162486.
↑ Zhang, Xiayi; Song, Li; Hong, Mingwei; Shi, Hongsheng; Xu, Kaijie; Lin, Qizhong; Zhao, Yi; Tian, Yuan; Sun, Jiafeng; Shu, Kangying; Chai, Wenxiang (2014). “Luminescent dinuclear copper(I) halide complexes double bridged by diphosphine ligands: Synthesis, structure characterization, properties and TD-DFT calculations”. 《Polyhedron》 (Elsevier BV) 81: 687–694. doi:10.1016/j.poly.2014.07.034. ISSN 0277-5387.

[1] Shatunov, V.V.; Korlyukov, A.A.; Lebedev, A.V.; Sheludyakov, V.D.; Kozyrkin, B.I.; Orlov, V.Yu. (2011). “The synthesis and deep purification of GaEt3. Reversible complexation of adducts MAlk3 (M = Al, Ga, In; Alk = Me, Et) with phenylphosphines”. 《Journal of Organometallic Chemistry》 (Elsevier BV) 696 (10): 2238–2251. doi:10.1016/j.jorganchem.2010.11.044. ISSN 0022-328X.

[2] Chou, Ta Shue; Yuan, Jeh Jing; Tsao, Chung Huang (1985). “Ultrasonic acceleration of the reductive cleavage of phosphorus-carbon bonds with lithium metal. A simple preparation of tertiary phosphines”. 《Journal of Chemical Research, Synopses》 (1): 18–19. ISSN 0308-2342. .

[3] Honaker, Matthew T.; Salvatore, Ralph Nicholas (2004년 2월 1일). “A MILD AND EFFICIENT CsOH-PROMOTED SYNTHESIS OF DITERTIARY PHOSPHINES”. 《Phosphorus, Sulfur, and Silicon and the Related Elements》 (Informa UK Limited) 179 (2): 277–283. doi:10.1080/10426500490262261. ISSN 1042-6507. S2CID 98162486.

[4] Zhang, Xiayi; Song, Li; Hong, Mingwei; Shi, Hongsheng; Xu, Kaijie; Lin, Qizhong; Zhao, Yi; Tian, Yuan; Sun, Jiafeng; Shu, Kangying; Chai, Wenxiang (2014). “Luminescent dinuclear copper(I) halide complexes double bridged by diphosphine ligands: Synthesis, structure characterization, properties and TD-DFT calculations”. 《Polyhedron》 (Elsevier BV) 81: 687–694. doi:10.1016/j.poly.2014.07.034. ISSN 0277-5387.

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